New derivative of heteroannulated chromeno[2,3-b]pyridine is constructed as CDPD structure.
Three direct allowed transitions were observed with band gaps of 1.17, 2.24 and 3.40 eV.
Strong PL intensity indicates an enhancement of optical characteristics of CDPD.
Heterojunctions of CDPD/p-Si show high rectification characteristics.
Heterojunctions of CDPD/p-Si indicate high photosensitivity under light illumination.