Novel fluorite Pr0.1Gd0.1Ce0.8O2−δ and spinel CoFe2O4 dual phase hollow fiber is developed.
Membrane robustness is verified by operating at 950 °C for 200 h in pure CO2 atmosphere.
The O2 flux swept by pure CO2 is 0.40 mL min−1 cm−2 higher than conventional membranes.
Robust O2 permeable membranes have potentials in clean energy and green chemical synthesis.