A novel CO2-resistant ceramic dual-phase hollow fiber membrane for oxygen separation
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Novel fluorite Pr0.1Gd0.1Ce0.8O2−δ and spinel CoFe2O4 dual phase hollow fiber is developed.

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Membrane robustness is verified by operating at 950 °C for 200 h in pure CO2 atmosphere.

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The O2 flux swept by pure CO2 is 0.40 mL min−1 cm−2 higher than conventional membranes.

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Robust O2 permeable membranes have potentials in clean energy and green chemical synthesis.

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