Size-selective epoxidation of olefins in two new metal-organic framework constructed from six-coordinated tetranuclear Cu(II) SBUs
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- 作者：Chao Chena ; chaochen@ncu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Pan Shena ; Mingming Wana ; Nan Dinga ; Xiaotong Shib ; Xiaolei Wangb ; Ning Zhanga ; nzhang.ncu@163.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：MOFs ; Six-coordinated SBUs ; Epoxidation of olefins ; Size-selectivity
- 刊名：Microporous and Mesoporous Materials
- 出版年：2016
- 出版时间：15 September 2016
- 年：2016
- 卷：232
- 期：Complete
- 页码：167-173
- 全文大小：1886 K
文摘
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Two new MOFs constructed from novel six-coordinated tetranuclear Cu(II) SBUs have been synthesized.
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The two MOFs present class="boldFont">flu-3,6-Fddd and class="boldFont">ant topological structures, respectively.
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The two MOFs exhibit good size-selectivity for the epoxidation of different olefin substrates.
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The possible catalytic mechanism for the reaction has been proposed.