Thermodynamic universality of configurational entropy in glass-forming liquids
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文摘
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Give one concise, explicit thermodynamic expression in T and P for the configurational entropy, showing its excellent universal description of experimental data.

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Generalize most important dynamic equations in the field and integrate two key thermodynamic variables in a single form.

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The formula has no singularity of divergence and thus plausibly resolves the long-standing Kauzmann paradox.

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The analysis indicates the glass transition as a second-order phase transition.

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Offer an organizing principle to rationalize the dynamic properties and advance researches on the thermodynamics including the glass transition of glass-formers.

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