A promising two-dimensional solar cell donor: Black arsenic-phosphorus monolayer with 1.54 eV direct bandgap and mobility exceeding 14,000 cm2 V−1 s−1
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Monolayer α–AsP as highly efficient donor for XSCs is proposed.

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α–AsP has direct gap (1.54 eV) and high electron mobility (14,380 cm2 V−1 s−1).

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We design a α–AsP/GaN XSC with maximum PCE of 22.1%.

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