Gypsum scaling in forward osmosis: Role of membrane surface chemistry
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Gypsum scaling in FO was compared between CTA and TFC membranes.

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Gypsum scaling of CTA membrane was dominated by bulk crystallisation.

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Gypsum scaling of TFC membrane was driven by surface crystallisation.

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No interaction –OH on CTA membrane was demonstrated in gypsum scaling.

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FTIR and XPS show interaction between –COOH on TFC membrane with Ca2+.

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