Study of the Molecular Recognition Mechanism of an Ultrathin MIP Film-Based Chiral Electrochemical Sensor
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- 作者：Bogdan-Cezar Iacoba ; 1 ; 2 ; iacob.cezar@umfcluj.ro" class="auth_mail" title="E-mail the corresponding author ; Ede Bodokia ; 1 ; 2 ; bodokie@umfcluj.ro" class="auth_mail" title="E-mail the corresponding author ; Cosmin Farcaub ; cosmin.farcau@phys.ubbcluj.ro" class="auth_mail" title="E-mail the corresponding author ; Lucian Barbu-Tudoranc ; lucian.barbu@ubbcluj.ro" class="auth_mail" title="E-mail the corresponding author ; Radu Opreana ; roprean@umfcluj.ro" class="auth_mail" title="E-mail the corresponding author
- 关键词：molecularly imprinted polymer ; molecular recognition ; chiral electrochemical sensor ; β-blocker ; ultra-thin film
- 刊名：Electrochimica Acta
- 出版年：2016
- 出版时间：1 November 2016
- 年：2016
- 卷：217
- 期：Complete
- 页码：195-202
- 全文大小：1862 K
文摘
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Atenolol’s particular MIP-based chiral recognition mechanism was investigated.
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Chiral recognition requires alternate exposure to aqueous and non-aqueous media.
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Enantiodiscrimination was studied both by a direct and indirect approach.
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Template rebinding significantly changes the permeability of the MIP-layer.
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An additional “gate effect” governs the molecular recognition process.