Synthesis, structure and photocatalytic hydrogen evolution of a silver-linked hexaniobate Lindqvist chain
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- 作者：Haiying Wang ; Zhijie Liang ; Qisen Liu ; Dongdi Zhang ; ddzhang@henu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Jingping Wang ; jpwang@henu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polyoxoniobate ; Lindqvist ; Transition metals ; Photocatalysis
- 刊名：Inorganic Chemistry Communications
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：61
- 期：Complete
- 页码：157-159
- 全文大小：511 K
文摘
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The compound represents the first example of Ag-incorporating polyoxoniobate.
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The synthetic strategy is the combination of hydrothermal and diffusional methods.
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The Ag ion is six-coordinated with tri-prism geometry.
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The compound class="boldFont">1 can be considered as an infinitely 1D chain built by [Nb6O19]8 − units through Ag bridges.