Charge ordering and exchange bias behaviors in Co3O4 porous nanoplatelets and nanorings
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Charge-ordered state appears for the Co3O4 nanoplatelets but absent for the nanorings.

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Quite significant exchange bias is only observed for Co3O4 nanorings.

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Exchange bias behavior of Co3O4 nanorings is consistent with spin-glass like shell.

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Potential for ultrahigh-density magnetic recording and spin valve devices.

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