Thermochemistry of 4-HOC6H4COR (R </ce:hsp>= </ce:hsp>H, CH3, C2H5, n-C3H7, n-C4H9, n-C5H11, and n-C6H13) compounds

Thermochemistry of 4-HOC₆H₄COR (R = H, CH₃, C₂H₅, n-C₃H₇, n-C₄H₉, n-C₅H₁₁, and n-C₆H₁₃) compounds

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作者：Cá ; tia S.D. Lopes ; Filipe Agapito ; Carlos E.S. Bernardes ; Manuel E. Minas da Piedade ; ^{memp@fc.ul.pt" class="auth_mail" title="E-mail the corresponding author}
刊名：Journal of Chemical Thermodynamics
出版年：2017
出版时间：January 2017
年：2017
卷：104
期：Complete
页码：281-287
全文大小：621 K

文摘

class="label">•: Enthalpies of vaporization/sublimation of 4-HOC₆H₄COR compounds were measured by Calvet microcalorimetry.
class="label">•: class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si1.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=4d1ad767d7461b8db6f2539d2ca8ce04">class="imgLazyJSB inlineImage" height="19" width="42" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si1.gif">class="mathContainer hidden">class="mathCode"> $Δ_{f} H_{m}^{°}$ (g) of 4-HOC₆H₄COR compounds were obtained from W1-F12 and CCSD(T)-F12 ab initio calculations.
class="label">•: The corresponding class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si1.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=4d1ad767d7461b8db6f2539d2ca8ce04">class="imgLazyJSB inlineImage" height="19" width="42" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si1.gif">class="mathContainer hidden">class="mathCode"> $Δ_{f} H_{m}^{°}$ (cr) were derived from the experimental class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si3.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=293c670869c50c567e116f6e8713b457">class="imgLazyJSB inlineImage" height="19" width="55" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si3.gif">class="mathContainer hidden">class="mathCode"> $Δ_{vap} H_{m}^{°}$ or class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si4.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=2f348829732efcced711b7f5bd307e12">class="imgLazyJSB inlineImage" height="20" width="53" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si4.gif">class="mathContainer hidden">class="mathCode"> $Δ_{sub} H_{m}^{°}$ data and the computational class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si1.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=4d1ad767d7461b8db6f2539d2ca8ce04">class="imgLazyJSB inlineImage" height="19" width="42" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si1.gif">class="mathContainer hidden">class="mathCode"> $Δ_{f} H_{m}^{°}$ (g) results.
class="label">•: The class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si4.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=2f348829732efcced711b7f5bd307e12">class="imgLazyJSB inlineImage" height="20" width="53" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si4.gif">class="mathContainer hidden">class="mathCode"> $Δ_{sub} H_{m}^{°}$ values show an approximately additive increase with the number of carbon atoms in the alkyl side chain.
class="label">•: An excellent linear correlation was found between the class="mathmlsrc">title="View the MathML source" class="mathImg" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0021961416302853&_mathId=si1.gif&_user=111111111&_pii=S0021961416302853&_rdoc=1&_issn=00219614&md5=4d1ad767d7461b8db6f2539d2ca8ce04">class="imgLazyJSB inlineImage" height="19" width="42" alt="View the MathML source" title="View the MathML source" src="/sd/grey_pxl.gif" data-inlimgeid="1-s2.0-S0021961416302853-si1.gif">class="mathContainer hidden">class="mathCode"> $Δ_{f} H_{m}^{°}$ (g) values and the number of carbon atoms in the alkyl side chain.

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