Quenching of electron transfer reactions through coadsorption: A study of oxygen photodesorption from TiO2(110)
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- 作者：Nikolay G. Petrik ; Greg A. Kimmel ; Mingmin Shen1 ; Michael A. Henderson ; ma.henderson@pnnl.gov" class="auth_mail" title="E-mail the corresponding author
- 关键词：Photodesorption ; TiO2(110) ; Oxygen ; Photochemistry ; Coadsorption
- 刊名：Surface Science
- 出版年：2016
- 出版时间：October 2016
- 年：2016
- 卷：652
- 期：Complete
- 页码：183-188
- 全文大小：818 K
文摘
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O2 photodesorption from the rutile TiO2(110) surface is suppressed by the coadsorption of a variety of species.
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Level of photochemical suppression correlates with binding energy of the coadsorbate.
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Modification of interfacial dipole by an adsorbed layer impacts photochemistry on TiO2(110).