Mixed matrix membranes based on UiO-66 MOFs in the polymer of intrinsic microporosity PIM-1
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- 作者：Muhanned R. Khdhayyera ; Elisa Espositob ; Alessio Fuocob ; Marcello Monteleoneb ; Lidietta Giornob ; Johannes C. Jansenb ; johannescarolus.jansen@cnr.it" class="auth_mail" title="E-mail the corresponding author ; Martin P. Attfielda ; Peter M. Budda ; Peter.Budd@manchester.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Mixed matrix membranes ; PIM-1 ; MOFs ; UiO-66 ; Gas transport ; Maxwell model
- 刊名：Separation and Purification Technology
- 出版年：2017
- 出版时间：1 February 2017
- 年：2017
- 卷：173
- 期：Complete
- 页码：304-313
- 全文大小：1365 K
文摘
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Metal Organic Frameworks UiO-66 improve the performance of PIM-1 gas separation membranes.
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The separation performance of the MMMs exceeds the 2008 Robeson upper bound for various gas pairs.
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The effect of UiO-66 on PIM-1 can be described by the Maxwell model.
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Methanol treatment greatly enhances the permeability.
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Mixed gas permeation experiments confirm an excellent separation performance.