Physicochemical study of solution behavior of ionic liquid prevalent in diverse solvent systems at different temperatures
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- 作者：Biswajit Datta ; Mahendra Nath Roy ; mahendraroy2002@yahoo.co.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ion-pair and triple-ion formation ; Limiting apparent molar volumes ; Viscosity B-coefficients ; FTIR study
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：16 November 2016
- 年：2016
- 卷：665
- 期：Complete
- 页码：85-94
- 全文大小：2275 K
文摘
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The IL, 1-butyl-4-methylpyridinium hexafluorophosphate [bmpy]PF6 forms ion-pair in ACN and forms triple-ion in DO and THF.
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Ion-solvent interaction increases with increase of temperature.
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The extent of ion-solvent interaction of [bmpy]PF6 is amplified in the following order: DO > THF > ACN.