Molecular structure and protonation trends in 6-methoxy- and 8-methoxy-2,4,5-tris(dimethylamino)quinolines
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- 作者：O.V. Dyabloa ; A.F. Pozharskiia ; apozharskii@sfedu.ru" class="auth_mail" title="E-mail the corresponding author ; E.A. Shmoilovaa ; V.A. Ozeryanskiia ; N.S. Fedika ; K.Yu. Suponitskyb
- 关键词：Quinolines ; 4 ; 5-Bis(dimethylamino)quinoline ; Proton sponges ; Protonation ; Molecular structure ; Basicity
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：5 March 2016
- 年：2016
- 卷：1107
- 期：Complete
- 页码：305-315
- 全文大小：1378 K
文摘
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Strong basicity interplay between aza- and peri-NMe2 groups in quinolines was studied.
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6- and 8-Methoxy-2,4,5-tris(dimethylamino)quinolines display different protonation mode.
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6-Methoxy-2,4,5-tris(dimethylamino)quinoline is the most basic of quinolines ever known.