Incorporation of low energy activated nitrogen onto HOPG surface: Chemical states and thermal stability studies by in-situ XPS and Raman spectroscopy
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Nitrogen incorporation onto HOPG was carried out by RF N2 plasma and N2+ implantation.

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Chemical state analyses of the modified HOPG surface were compared by in-situ XPS.

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Formation of chemical bonding states are influenced by the process of nitridation.

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N+ implantation process resulted in a high level of defects to the uppermost surface.

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RF N2 plasma process incorporated stable nitrogen species with less surface defects.

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