Chemical compatibility between garnet-like solid state electrolyte Li6.75La3Zr1.75Ta0.25O12 and major commercial lithium battery cathode materials
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- 作者：Yaoyu Ren ; yroneal@gmail.com" class="auth_mail" title="E-mail the corresponding authorAuthor Vitae ; Ting Liu liuting20002000@163.com" class="auth_mail" title="E-mail the corresponding author ; Yang Shen shyang_mse@mail.tsinghua.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Yuanhua Lin linyh@mail.tsinghua.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Ce-Wen Nan cwnan@mail.tsinghua.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Cathodes ; Garnet-type solid electrolyte ; Reactivity
- 刊名：Journal of Materiomics
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：2
- 期：3
- 页码：256-264
- 全文大小：3414 K
文摘
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LiMn2O4 (LMO) and LiFePO4 (LFP) were found to react with Li6.75La3Zr1.75Ta0.25O12 (LLZTO) at about 500 °C by X-ray diffraction.
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LiCoO2 (LCO) and LiNi0.33Co0.33Mn0.33O2 (NCM) were found to react with LLZTO at about 700 °C by Raman spectra.
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LaCoO3 is one possible reaction product between LCO and LLZTO. LaCo1−xMnxO3 is one possible reaction product between NCM and LLZTO.