Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397-0.499)
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- 作者：Anthony J. Cortese ; Dileka Abeysinghe ; Mark D. Smith ; Hans-Conrad zur Loye ; zurloye@mailbox.sc.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Molybdenum(V) ; Metal reducing agent ; In situ reduction ; Magnetism ; Crystal growth
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：August 2016
- 年：2016
- 卷：240
- 期：Complete
- 页码：76-81
- 全文大小：627 K
文摘
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Six lanthanide sodium molybdates have been synthesized and characterized.
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An in situ reduction was carried out using Mo as a metal reducing agent.
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UV/Vis and magnetic susceptibility data were collected.
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Eu0.603(2)Na0.397(2)MoO4 was found to possess the highest Mo5+ content at 20.6%.