Multiferroic behavior of the Bi0.9La0.1Fe1−xNbxO3+x (x≤0.02) ceramics was studied.
The compounds crystallize with a polar rhombohedral structure.
Nb doping results in decreasing the size of crystal grains and ferroelectric domains.
The doping induces antiferromagnetic-weak ferromagnetic transformation.
The magnetic and morphological changes can be understood as lattice defects-driven.