Heterothiometallic clusters as robust and efficient copper(I) catalysts for azide-alkyne [3 + 2] cycloadditions
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- 作者：Xiao-Fei Gaoa ; Wen-Mei Suna ; Xiao-Miao Lia ; Xiao-Jun Liua ; Long-Sheng Wangb ; Zheng Liua ; Jun Guoa ; jguo@mail.ccnu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：W(Mo)/S/Cu clusters ; Copper ; Click chemistry ; Solvent-free reaction
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 January 2016
- 年：2016
- 卷：73
- 期：Complete
- 页码：103-108
- 全文大小：989 K
文摘
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Heterothiometallic W(Mo)/S/Cu clusters were developed as novel copper(I) catalysts.
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W(Mo)/S/Cu clusters can stabilize copper(I) ions and improve their solubility.
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[NH4]2[WS4Cu4I4] is a robust and efficient catalyst for CuAAC reactions.
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20">CuAAC reactions were performed under polar solvent or solvent-free conditions.