Ultrafast vibrational energy flow in water monomers in acetonitrile
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- 作者：Fabian Dahms ; Rene Costard ; Erik T.J. Nibbering ; Thomas Elsaesser ; elsasser@mbi-berlin.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ultrafast infrared spectroscopy ; Hydrogen bond dynamics ; Vibrational relaxation
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：16 May 2016
- 年：2016
- 卷：652
- 期：Complete
- 页码：50-55
- 全文大小：1500 K
文摘
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Femtosecond two-color pump–probe experiments on water monomers in acetonitrile.
Separation of anharmonic coupling and population transfer between OH stretching and bending modes.
First direct evidence for OH stretch relaxation via OH bending mode.