Visible light induced oxygenation of alkenes with water sensitized by silicon-porphyrins with the second most earth-abundant element
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- 作者：Sebastian Nybin Remello ; Takehiro Hirano ; Fazalurahman Kuttassery ; Yu Nabetani ; Daisuke Yamamoto ; Satomi Onuki ; Hiroshi Tachibana ; Haruo Inoue ; inoue-haruo@tmu.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Artificial photosynthesis ; Water oxidation ; Oxygenation ; Silicon ; Visible light ; Porphyrin
- 刊名：Journal of Photochemistry & Photobiology, A: Chemistry
- 出版年：2015
- 出版时间：1 December 2015
- 年：2015
- 卷：313
- 期：Complete
- 页码：176-183
- 全文大小：1994 K
文摘
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Si(IV)-porphyrin induces the photochemical oxygenation of alkenes with water.
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Water serves as both electron and oxygen atom donor.
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The Si(IV) utilized is the Earth's the second most abundant element.