Polyoxometalate immobilized in MIL-101(Cr) as an efficient catalyst for water oxidation
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- 作者：Jianyu Hana ; b ; Danping Wangc ; YongHua Dud ; Shibo Xid ; Zhong Chenc ; Shengming Yina ; Tianhua Zhoua ; Rong Xua ; e ; rxu@ntu.edu.sg" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polyoxometalates ; MIL-101 ; Water oxidation ; Photocatalysis ; Electrocatalysis
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：5 July 2016
- 年：2016
- 卷：521
- 期：Complete
- 页码：83-89
- 全文大小：1974 K
文摘
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Polyoxometalate (CoPOM) is immobilized in cavities of MIL-101(Cr) with a good dispersion by a facile ion exchange method.
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Immobilized CoPOM exhibits enhanced photocatalytic and electrocatalytic water oxidation activities and improved stability due to its interaction wit MIL-101.
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Heterogenization of homogeneous CoPOM makes it easier to be recycled.