Synthesis and characterisation of derivatives of [HIr₄(CO)₁₀(μ-PPh₂)] with mono and diphosphines; X-ray molecular structures of [HIr₄(CO)₈(P

详细信息    查看全文

• 作者：Ziglio ; Clá ; udio M. ; Vargas ; Maria D. ; Braga ; Dario ; Grepioni ; Fabrizia ; Nixon ; John F.
• 关键词：Cluster ; Iridium ; Phosphines ; Carbonyl ; Isomerisation
• 刊名：Journal of Organometallic Chemistry
• 出版年：2002
• 出版时间：August 15, 2002
• 年：2002
• 卷：656
• 期：1-2
• 页码：188-198
• 全文大小：261 K

文摘

The reactions of the cluster compound [HIr₄(CO)₁₀(μ-PPh₂)] (1) with a series of phosphines, PMe₃ and PPh₃, and diphosphines, Ph₂P(CH₂)_nPPh₂ (n