Depressurization experiment of pressure cores from the central Ulleung Basin, East Sea: Insights into gas chemistry

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• 作者：Ji-Hoon Kim ; Marta E. Torres ; Joo Yong Lee ; Wei-Li Hong ; Melanie Holl ; Myong-Ho Park ; Jiyoung Choi ; Gil-Young Kim
• 刊名：Organic Geochemistry
• 出版年：2013
• 出版时间：September, 2013
• 年：2013
• 卷：62
• 期：Complete
• 页码：86-95
• 全文大小：2882 K

文摘

We performed depressurization experiments on pressure cores (PCs) recovered from Holes UBGH1-10B and UBGH2-11B, which were drilled during two separate expeditions in the Ulleung Basin (UBGH1 and UBGH2). Various lines of evidence, such as convex curvature in the P-V curves obtained by depressurization, as well as X-ray images and resistivity-at-bit (RAB) data, point to the presence of gas hydrates at these holes. We estimated gas hydrate saturation (S_h) at these holes to range from 5-23 % , based on the amount of gas released from PCs. These S_h values are in agreement with those reported at other high gas flux settings.

Molecular (C₁/C₂₊) and isotopic (¦Ä¹³C_CH4, ¦ÄD_CH4, ¦Ä¹³C_C2H6) indicators delineate a microbial source for the CH₄ and C₂H₆. In Core UBGH1-10B-5R, the carbon isotopic fractionation factor between CO₂ and CH₄ (¦Å_c ¡Ö ¦Ä¹³C_CO2 ? ¦Ä¹³C_CH4) was observed to increase from 50 to 68 as pressure was reduced during our experiments. These changes illustrate the isotope fractionation that results from the preferential release of ¹³C depleted CO₂ during the early stages of depressurization.

The constant carbon isotope separation (¡«10-20¡ë) between CO₂ in void gases and in the dissolved inorganic carbon (DIC) pool shown in cores from the Ulleung Basin, has also been observed in gas hydrate-bearing sediments elsewhere. It is important to consider this effect when using carbon isotopic data in carbon cycling models, specifically when unraveling metabolic pathways of methane generation. In situations where partial CO₂ degassing of a core is suspected, we recommend the use of the carbon isotope ratio of DIC instead of the gas measurements to best delineate the methane cycling pathways in marine systems.