Crystalline arrays of side chain modified bile acids derivatives. Two novel self-assemblies based on π-π and belly-to-belly interactions
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- 作者：Martha C. Mayorquí ; n-Torresa ; Rafael Arcos-Ramosb ; Marcos Flores-Á ; lamoa ; Martí ; n A. Iglesias-Arteagaa ; martin.iglesias@unam.mx" class="auth_mail" title="E-mail the corresponding author
- 关键词：Side chain modified bile acids ; Single X-ray diffraction ; Crystalline arrays ; π-Stacking ; Steroidal supramolecular self-assemblies
- 刊名：Steroids
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：115
- 期：Complete
- 页码：169-176
- 全文大小：2532 K
文摘
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Crystalline 24-(4′-methoxycarbonyl-phenyl)-5β-cholan-24-ones were obtained.
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Side chain modified bile acid derivatives display novel crystal packing motifs.
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Novel self-assemblies are dominated by π-π and belly-to-belly interactions.
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Two compounds form columnar arrays joined by π-π stacked side chains.