Verstile silver(I) and nickel(II) NHC complexes bearing benzotriazole-function: Synthesis, fluorescence and catalytic property
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- 作者：Zhan He ; Shu-Fang Zhang ; Jun-Ru Xue ; Yue Liang ; Xia Zhang ; Lin-Hai Jing ; Da-Bin Qin ; qdbkyl@cwnu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Benzotriazole derivatives ; NHC complexes ; Metallamacrocycles ; Catalytic activity
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：808
- 期：Complete
- 页码：12-22
- 全文大小：1897 K
文摘
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Ag, Ni–NHCs were synthesized and characterized by elemental analysis, NMR and X-ray diffraction.
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Complexes 5 and 6 formed 1D and 2D supramolecular chains.
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Complex 7 afford the dinuclear Ag metallamacrocycles.
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Complex 4 exhibits moderate catalytic activity in the Suzuki−Miyaura cross-coupling reaction.