Highly selective and sensitive detection of F^{∿/sup> and CN∿/sup> ions simultaneously by a reaction-based BODIPY-containing conjugated polymer}

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• 作者：Lingyun Wang ; ^{lingyun@scut.edu.cn" class="auth_mail" title="E-mail the corresponding author}Author Vitae ; Guipo FangAuthor Vitae ; Derong CaoAuthor Vitae
• 关键词：Colorimetric ; Ratiometric ; BODIPY ; Conjugated polymer ; Anions
• 刊名：Sensors & Actuators: B. Chemical
• 出版年：2015
• 出版时间：31 December 2015
• 年：2015
• 卷：221
• 期：Complete
• 页码：63-74
• 全文大小：3580 K

文摘

A new BODIPY-containing conjugated polymer (P1) had been designed and synthesized as a colorimetric and fluorescent chemosensor for F⁻ and CN⁻. The combination of advantages of both reaction based sensors and conjugated polymer sensors offered its highly sensitive and selective recognition of F⁻ and CN⁻ with no interference from each other. The addition of F⁻ and CN⁻ to P1 solution induced a rapid color change from purple to orange and faint yellow, respectively. At the same time, the emission color of the P1 solution changed from red to yellow and yellowish green in presence of F⁻ and CN⁻, respectively. ¹¹B, ¹⁹F and ¹H NMR spectra indicated that addition of fluoride and cyanide result in a nucleophilic displacement to break a BN bond of P1. In addition, the cell imaging experiments demonstrated that P1 could be successfully applied as a bioimaging agent with good biocompatibility.