Reactivity descriptors for ceria in catalysis
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- 作者：Març ; al Capdevila-Cortadaa ; Gianvito Vilé ; b ; Detre Teschnerc ; teschner@fhi-berlin.mpi.de" class="auth_mail" title="E-mail the corresponding author ; Javier Pé ; rez-Ramí ; rezb ; jpr@chem.ethz.ch" class="auth_mail" title="E-mail the corresponding author ; Nú ; ria Ló ; peza ; nlopez@iciq.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ceria ; Structure-activity relationships ; Oxidation ; Hydrogenation ; Acid-base ; Redox
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：15 November 2016
- 年：2016
- 卷：197
- 期：Complete
- 页码：299-312
- 全文大小：3389 K
文摘
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The catalytic performance of ceria has been systematized in terms of chemical descriptors.
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Basicity and redox properties contribute simultaneously to several catalytic phenomena.
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Experimental rates can be quantitatively expressed by combinations of the chemical descriptors.
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These chemical descriptors can be extended to other oxides.