An unusual cis-phosphonodithioato Pd(II) complex in an extensive hydrogen bonding 3D network
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- 作者：Carla Aragoni ; Maria ; Arca ; Massimiliano ; Demartin ; Francesco ; Devillanova ; Francesco A. ; et. al.
- 关键词：Supramolecular chemistry ; Phosphonodithioato ligands ; Pd ; X-ray crystal structure
- 刊名：Inorganica Chimica Acta
- 出版年：2005
- 出版时间：January 1, 2005
- 年：2005
- 卷：358
- 期：1
- 页码：213-216
- 全文大小：386 K
文摘
The PaaaN bond hydrolysis of the 4-methoxyphenyl-ammoniumethylamido-phosphonodithioato ligand on complexation to PdII leads to the first example of a Pd-phosphonodithioato complex in a cis configuration, stabilised in the solid state by an extended network of hydrogen bondings involving the released ethylenediamine and a water molecule.