Synthesis and cross-coupling reactions of imidomethyltrifluoroborates with aryl chlorides

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• 作者：Rammohan Devulapally^a ; Nicolas Fleury-Bré ; geot^b ; Gary A. Molander^b ; ^{gmolandr@sas.upenn.edu} ; Dave G. Seapy^a ; ^{dave.seapy@qatar.tamu.edu}
• 关键词：Potassium imidomethyltrifluoroborates ; Suzuki&ndash ; Miyaura cross-coupling reaction ; N-Benzylphthalimides
• 刊名：Tetrahedron Letters
• 出版年：2012
• 出版时间：29 February, 2012
• 年：2012
• 卷：53
• 期：9
• 页码：1051-1055
• 全文大小：917 K

文摘

Potassium imidomethyltrifluoroborate salts were efficiently synthesized. Potassium phthalimidomethyltrifluoroborate was successfully used in Suzuki-Miyaura-like cross-coupling reactions with a variety of aryl chlorides.