Solvent free, palladium catalyzed highly facile synthesis of diaryl disulfides from aryl thiols

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• 作者：Pratip Kumar Dutta^a ; ¹ ; Arpi Majumder^b ; ¹ ; Sanjay Dutta^a ; Basab Bijayi Dhar^a ; Parthapratim Munshi^a ; Subhabrata Sen^a ; ^{subhabrata.sen@snu.edu.in}
• 关键词：Diaryl disulfides ; Aryl thiol ; Pd(pCH2S)2dba ; Green chemistry ; DFT calculations
• 刊名：Tetrahedron Letters
• 出版年：2017
• 出版时间：8 February 2017
• 年：2017
• 卷：58
• 期：6
• 页码：527-530
• 全文大小：627 K
• 卷排序：58

文摘

Solvent free condition. 5 mol% of Pd(CH2PS)2dba. Diverse aryl thiols are converted to corresponding diaryl disulfides. Putative mechanism is proposed through DFT calculations.