Rydberg and valence excited states of dibromomethane in 35,000-95,000 cm鈭? region studied using synchrotron radiation
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- 作者：Anuvab Mandala ; Param Jeet Singhb ; singhp@barc.gov.in" class="auth_mail ; Aparna Shastrib ; Vijay Kumarc ; B.N. Raja Sekharb ; B.N. Jagatapa
- 关键词：Dibromomethane ; Vacuum ultraviolet spectrum ; Rydberg series ; Valence states ; TDDFT calculation ; Synchrotron radiation
- 刊名：Journal of Quantitative Spectroscopy and Radiative Transfer
- 出版年：September 2014
- 年：2014
- 卷：144
- 期：Complete
- 页码：164-173
- 全文大小：694 K
文摘
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VUV spectroscopy of CH2Br2 using synchrotron radiation and TDDFT calculations.
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Assignments of np and nd series for the first time and revised assignments of ns series.
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Vibrational bands assigned to 谓3 in contrast to earlier assignments of 谓2 and 谓3.
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Valence states identified responsible for underlying intensity in VUV spectrum.
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First VUV study of CD2Br2, used to consolidate Rydberg and vibronic assignments.