Formation of 2,6-dichloro-1,4-benzoquinone from aromatic compounds after chlorination

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• 作者：Koji Kosaka^a ; ^{kosaka@niph.go.jp} ; Takahiko Nakai^b ; Yuta Hishida^c ; Mari Asami^a ; Keiko Ohkubo^a ; Michihiro Akiba^d
• 关键词：2 ; 6-Dichloro-1 ; 4-benzoquinone ; Phenol ; para-Substituted phenolic compound ; 3 ; 5-Dichloroquinone-4-chloroimide ; para-Substituted aromatic amine ; Chlorination
• 刊名：Water Research
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：110
• 期：Complete
• 页码：48-55
• 全文大小：915 K
• 卷排序：110

文摘

DCBQ was formed from 21 of 31 model aromatic compounds after chlorination. Molar formation yields of DCBQ after 60 min ranged from 0.0008% to 4.9%. DCBQ formation from para-substituted phenols was found. DCBQ formation from para-substituted aromatic amines via 3,5-DCQC was found.