Electrochemical synthesis of benzoxazoles mediated by 2,3-dichloro-5,6-dicyano-p-hydroquinone (DDH) as a redox catalyst
详细信息 查看全文
- 作者：Li-Shuo Kanga ; Huan-lan Xiaoa ; Cheng-Chu Zenga ; zengcc@bjut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Li-Ming Hua ; R. Daniel Littleb
- 关键词：Indirect electrolysis ; 2 ; 3-Dichloro-5 ; 6-dicyano-p-hydroquinone (DDH) ; 2 ; 3-Dichloro-5 ; 6-dicyano-1 ; 4-benzoquinone (DDQ) ; Benzoxazole ; Schiff base
- 刊名：Journal of Electroanalytical Chemistry
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：767
- 期：Complete
- 页码：13-17
- 全文大小：1037 K
文摘
- •
The first report of the electrochemical cyclization of Schiff bases leading to benzoxazoles using DDH as a mediator.
- •
1005">The presence of 2,6-lutidine facilitiates the deprotonation.
- •
1010">The chemistry was performed in a beaker type undivided cell under constant current electrolysis conditions.