Schottky behavior (ΦB = 0.41 eV) and Fermi level pining were found pre annealing. Ni2Si formation was confirmed for 5 min at 850 °C. 3C/Ni2Si Fermi level alignment is responsible for ohmic contact behavior. Wet chemical etching (Si–OH/C–H termination) does not impair Ni2Si formation.