(1−x)[BZT-0.5BCT]-x[NZF] composites were synthesized for the first time. Presence of MH and PE hysteresis loops confirm multiferroic nature of composites. Dielectric anomaly near magnetic transition of NZF confirms strong ME coupling. αE (12.95 mV/Oe.cm at 1 kHz and 254 mV/Oe.cm at 35 kHz of Hac)is maximum for x = 0.25.