4-(2,2-Dimethyldioxalan-4-yl)-5-(pterin-6-yl)-1,3-dithiol-2-ones Proligands Relating to the Cofactor of the Oxomolybdoenzymes

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• 作者：Dinsmore ; Andrew ; Garner ; C. David ; Joule ; John A.
• 刊名：Tetrahedron
• 出版年：1998
• 出版时间：August 13, 1998
• 年：1998
• 卷：54
• 期：33
• 页码：9559-9568
• 全文大小：519 K

文摘

The coupling of the 6-iodopterins <b>11eb> and <b>12db> to 4-(2,2-dimethyl-1,3-dioxolan-4-yl)-5-(tributylstannyl)-1,3-dithiol-2-one <b>8b> gave 4-(2-(N,N-dimethylaminomethyleneamino)-3-(2,2-dimethyl-propanoyloxymethyl)pteridin-4-on-6-yl)-5-(2,2-dimethyl-1,3-dioxolan-4-yl)-1,3-dithiol- 2-one <b>6b> and 4-(2-(2,2-dimethylpropanoylamino)-3-(2,2-dimethylpropanoyloxymethyl)pteridin-4-on-6-yl)-5-(2,2- dimethyl-1,3-dioxolan-4-yl)-1,3-dithiol-2-one <b>7b>, respectively.