Expanding the family of C,N-chelated organotin(IV) pseudohalides: Synthesis and structural characterization
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- 作者：Petr &Scaron ; veca ; Petr.Svec2@upce.cz" class="auth_mail" title="E-mail the corresponding author ; Zdeňka Růžičková ; a ; Petr Vlasá ; kb ; Jan Turekc ; Frank De Proftc ; Ale&scaron ; Růžičkaa
- 关键词：Organotin(IV) pseudohalides ; C ; N-chelating ligand ; XRD analysis ; NMR spectroscopy ; IR spectroscopy ; DFT calculations
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：801
- 期：Complete
- 页码：14-23
- 全文大小：1432 K
文摘
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Tri- and diorganotin(IV) pseudohalide complexes were prepared.
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C,N-chelating ligand was used in order to achieve monomeric species.
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N
CY ligands are bound to the tin atom via nitrogen while the CN substituent behaves as a common cyanide ligand.