Probing the excited state nature of coordination complexes with blended organic and inorganic chromophores using vibrational spectroscopy
详细信息 查看全文
- 作者：Raphael Horvatha ; Gregory S. Huffb ; Keith C. Gordonb ; keith.gordon@otago.ac.nz" class="auth_mail" title="E-mail the corresponding author ; Michael W. Georgea ; c ; Mike.George@nottingham.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Blended organic and inorganic chromophores ; Transient spectroscopy ; Coordination compounds
- 刊名：Coordination Chemistry Reviews
- 出版年：2016
- 出版时间：15 October 2016
- 年：2016
- 卷：325
- 期：Complete
- 页码：41-58
- 全文大小：4039 K
文摘
- •
The use of vibrational spectroscopy in determining types of excited states is discussed.
- •
Focus is given to metal polypyridyl complexes in which metal-to-ligand charge-transfer is important.
- •
More complex systems with a number of close lying low energy excited states are described, such as dipyridophenazine complexes.
- •
Engineered multichromophore systems are described in which there is weak and strong inter-chromophore coupling.