Transient spectroscopy of dipyridophenazine metal complexes which undergo photo-induced electron transfer with DNA

详细信息    查看全文

• 作者：Jayden A.  ; Smith^a ; Michael W.  ; George^b ;   ; ^{mike.george@nottingham.ac.uk} ; John M.  ; Kelly^a ;   ; ^{jmkelly@tcd.ie}
• 关键词：Dppz ; Dipyridophenzine ; DNA ; Electron transfer ; Metal complexes ; Ruthenium ; Chromium ; Rhenium ; Transient spectroscopy ; TRIR
• 刊名：Coordination Chemistry Reviews
• 出版年：2011
• 出版时间：November 2011
• 年：2011
• 卷：255
• 期：21-22
• 页码：2666-2675
• 全文大小：1148 K

文摘

This review considers transient spectroscopic studies of electron transfer reactions between nucleic acids and the excited states of transition metal complexes containing dipyridophenazine or related ligands and focuses mainly on complexes of ruthenium, chromium and rhenium. Particular emphasis is placed on systems where transient UV/visible and/or infrared absorption spectroscopy have been employed.