Synthesis of 5-O-oligoglucosyl extended α-(2→4)-Kdo disaccharides corresponding to inner core fragments of Moraxellaceae lipopolysaccharides
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- 作者：Barbara Pokorny ; Paul Kosma ; paul.kosma@boku.ac.at" class="auth_mail" title="E-mail the corresponding author
- 关键词：Oligosaccharide synthesis ; Acinetobacter ; Glycosylation ; Kdo ; Lipopolysaccharide
- 刊名：Carbohydrate Research
- 出版年：2016
- 出版时间：3 March 2016
- 年：2016
- 卷：422
- 期：Complete
- 页码：5-12
- 全文大小：430 K
文摘
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First synthesis of the branched inner core trisaccharide α-Glcp-(1→5)[α-Kdo-(2→4)]-α-Kdo related to Moraxellaceae lipopolysaccharides.
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Good stereoselectivity and a high yield for α-glucosylation of a Kdo disaccharide.
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Further extension gave tetra- and pentasaccharide fragments of the Acinetobacter haemolyticus LPS.