Electrochemical conversion of dinitrogen to ammonia induced by a metal complex-supported ionic liquid
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- 作者：Akira Katayamaa ; Tomohiko Inomatab ; Tomohiro Ozawaa ; c ; 1 ; Hideki Masudac ; 1 ; masuda.hideki@nitech.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Dinitrogen fixation ; Ionic liquid ; Transition metal complex ; Ammonia
- 刊名：Electrochemistry Communications
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：67
- 期：Complete
- 页码：6-10
- 全文大小：606 K
文摘
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The electrochemical synthesis of NH3 from N2 and proton by using Cp2TiCl2.
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The yield of NH3 per Cp2TiCl2 in ionic liquid was higher than that in organic solvent.
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The ionic liquid assists in the dissociation of Cl anion from the Cp2TiCl2 and promotes a decrease in the activation energy.