Multifaceted zirconate complexes in organic synthesis
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- 作者：Xiaoyu Yana ; Chanjuan Xia ; b ; cjxi@tsinghua.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ar ; aryl ; n-Bu ; n-butyl ; t-Bu ; t-butyl ; Cp ; η5-cyclopentadienyl ; DMAD ; dimethyl acetylenedicarboxylate ; DMAP ; 4-dimethylaminopyridine ; E+ ; electrophiles ; Et ; ethyl ; n-Hex ; n-hexyl ; Me ; methyl ; n-Oct ; n-octyl ; Ph ; phenyl ; rt ; room temperature ; TCNE ; tetracyanoethylene ; TCQ ; p-chloranil ; TMSOTf ; trimethylsilyl trifluoromethanesulfonate ; p-Tol ; p-tolyl
- 刊名：Coordination Chemistry Reviews
- 出版年：2016
- 出版时间：1 February 2016
- 年：2016
- 卷：308
- 期：part_P1
- 页码：22-31
- 全文大小：1772 K
文摘
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Unique reactivity of zirconate complexes toward electrophiles.
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Diverse reactivity patterns when different electrophiles employed.
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Synthesis of novel organic molecules by one-pot multi-component reactions.
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Reaction mechanisms for the reductive elimination and cross-coupling.