A ruthenium biimidazole-like anion receptor with two chelating NH鈰疧 intramolecular hydrogen bonds

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• 作者：Hao-Jun Mo ; Hsiu-Yi Chao ; Bao-Hui Ye
• 关键词：Anion receptor ; Biimidazole ; Intramolecular hydrogen bond ; Ruthenium
• 刊名：Inorganic Chemistry Communications
• 出版年：September, 2013
• 年：2013
• 卷：35
• 期：Complete
• 页码：100-103
• 全文大小：736 K

文摘

A new ruthenium biimidazole-like anion receptor featuring two 鈥渃helating鈥?NH鈰疧 intramolecular hydrogen bonds, [Ru(bpy)₂(DNBbimH₂)](PF₆)₂ (2路(PF₆)₂) (bpy = 2,2鈥?bipyridine; DNBbimH₂ = 5,5鈥?6,6鈥?tetramethyl-7,7鈥?dinitro-2,2鈥?bibenzimidazole), has been synthesized. Its anion-binding ability towards different anions in acetonitrile has been studied.