Efficient and recyclable Cu2(BPDC)2(DABCO)-catalyzed direct amination of activated sp3 CH bonds by N-H heterocycles
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- 作者：Thanh Truong ; tvtruong@hcmut.edu.vn" class="auth_mail" title="E-mail the corresponding author ; truongvuthanh@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Khoa D. Nguyen ; Son H. Doan ; Nam T.S. Phan ; ptsnam@hcmut.edu.vn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Metal-organic framework ; Cross-coupling ; Azoles ; Amides ; CN bond activation ; Heterogeneous catalyst
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：25 January 2016
- 年：2016
- 卷：510
- 期：Complete
- 页码：27-33
- 全文大小：1834 K
文摘
- •
First heterogeneous catalysts for direct couplings of activated sp3 C
hImg imgLazyJSB">H with N–H heterocycles.- •
Catalytic activity of Cu2(BPDC)2(DABCO) is comparable to that of homogeneous Cu salts.
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The catalyst can be facilely recovered and reused.