Tetranuclear LnIII2MnII2 cymantrenecarboxylates. Synthesis, structure, thermolysis and magnetic properties
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- 作者：Pavel S. Koroteev ; pskoroteev@list.ru" class="auth_mail ; Nikolay N. Efimov ; Andrey B. Ilyukhin ; Zhanna V. Dobrokhotova ; Vladimir M. Novotortsev
- 关键词：QUWODZMNVOLMCD-UHFFFAOYSA-I ; KOGBJBBSFXIVOK-UHFFFAOYSA-G
- 刊名：Inorganica Chimica Acta
- 出版年：1 July 2014
- 年：2014
- 卷：418
- 期：Complete
- 页码：157-162
- 全文大小：883 K
文摘
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3d–4f-heterometallic “defective dicubane” cymantrenecarboxylates were synthesized.
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Thermolysis of obtained complexes under air affords LnMn2O5 and Mn2O3 phases.
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Dy complex exhibits the properties of single molecule magnet.