Ni3S2@Ni 3D electrode was prepared by a novel corrosion method using sodium sulfide.
Corrosion method to Ni3S2@Ni is brought up by a process analysis based on physical chemistry.
3D electrode shows higher sensitivity and better dynamic response for hydrazine.
Ni3S2 is a promising substitute material for noble metal in hydrazine electro-oxidation.
Ni3S2 is revealed to be a promising material for hydrazine electro-oxidation.