Li2TiO3 and carbon co-coated LiMnPO4 with mixed conductive network is prepared.
Co-coated LiMnPO4 has better rate and cycle performance than the pristine one.
The capacity of 3 wt.% Li2TiO3-coated LiMnPO4 is 117.7 mAh g− 1 at 2 C between 2.5 and 4.5 V.