Tuning the surface chemistry of lubricant-derived phosphate thermal films: The effect of boron

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• 作者：F. Spadaro^a ; A. Rossi^a ; ^b ; ^{antonella.rossi@mat.ethz.ch} ; ^{rossi@unica.it} ; E. Lain&eacute ; ^c ; P. Woodward^c ; N.D. Spencer^a ; ^{nicholas.spencer@mat.ethz.ch}
• 关键词：Thermal film ; ZnDTP ; Borated dispersant ; NMR ; Angle-resolved XPS ; Layer thickness
• 刊名：Applied Surface Science
• 出版年：2017
• 出版时间：28 February 2017
• 年：2017
• 卷：396
• 期：Complete
• 页码：1251-1263
• 全文大小：1746 K
• 卷排序：396

文摘

The additives bulk interactions in “neat” blends at high temperatures is evaluated. The competition among the different additives to react with air-oxidized steel surfaces under pure thermal condition is investigated. Different thermal films are grown, their in depth-composition and thickness is determined by ARXPS. A reaction mechanism is proposed for elucidating the composition of the thermals films.