The first report of [2+2] ketene-imine cycloaddition reactions (Staudinger) on carbon nanotubes

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• 作者：Aliasghar Jarrahpour ; ^{jarrah@susc.ac.ir} ; ^{aliasghar6683@yahoo.com} ; Mohammad Mahdi Doroodmand ; Edris Ebrahimi
• 关键词：Staudinger reaction ; Carbon nanotube ; ¦Â-Lactam ; ¦Â-d-Glucopyranosylamine ; [2+2] Cycloaddition
• 刊名：Tetrahedron Letters
• 出版年：2012
• 出版时间：6 June, 2012
• 年：2012
• 卷：53
• 期：23
• 页码：2797-2801
• 全文大小：2244 K

文摘

Several new carbon nanotube-functionalized ¦Â-lactams have been synthesized from chiral imines derived from ¦Â-d-glucopyranosylamine and a ketene from carbon nanotube-based oxyacetic acid via a [2+2] cycloaddition reaction. The cycloadducts were characterized by thermogravimetric analysis, Raman spectrometry, IR, and N₂ adsorption processes.